Electrochemical sensors for the determination of Ba(II) ions

Elmosallamy, Mohamed Alaa Eldeen; Hashem, Hassan; Abdalmoez, Fatma

doi:10.21608/bfszu.2023.228835.1296

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	Electrochemical sensors for the determination of Ba(II) ions
Article 18, Volume 2024, Issue 2, July 2024, Page 174-181 PDF (680.41 K)
Document Type: Original Article
DOI: 10.21608/bfszu.2023.228835.1296
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Authors
Mohamed Alaa eldeen Elmosallamy ¹; Hassan Hashem²; Fatma Abdalmoez³
¹Faculty of Science Zagazig University
²Department of Physics, Faculty of Science, Zagazig University, Zagazig
³Faculty of Science, Zagazig University, Zagazig
Abstract
Two solid-state membrane and coated wire electrochemical sensors have been developed based on barium sulphate nanoparticles. BaSO4 nanoparticles are synthesized by the chemical co-precipitation technique. BaSO4 nanoparticles disc used to design the solid- state membrane sensor and the BaSO4 nanoparticles utilized to fabricate the coated wire sensor. The two sensors display linear responses over the concentration ranges of 1.0×10-5-1.0×10-1mol L-1 Ba2+ ions with cationic slopes of 25.7±0.1732and 29.8±1.29615 mV decade-1 for the solid-state membrane and coated wire sensors, respectively. The lower limits of detection are 2.7×10-6 and 2.5×10-6 mol L-1 Ba2+ ions for the solid-state membrane and coated wire sensors, respectively. The response time for the two sensors is instantaneous (1 s), the useful life span for the solid-state membrane and coated wire sensors are 2 and 8 months, respectively. ThepH profile is studied and it is found that the two sensors have a wide range of used pH.the two sensors have a higher selectivity for Ba2+ ions over mono, bi, and trivalent metal ions
Keywords
Electrochemical sensors; Barium(II); solid- state membrane sensor; coated wire sensor
Main Subjects
Basic and applied research of Chemistry,


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